A number of countries throughout the world
are trying to develop alternative fuels in order to reduce
air pollution and reduce import oil costs (http://www.chemweb.com/alchem/articles/
992513141289.html). Ethanol is a clean-burning fuel that has
been used on an experimental basis to run cars in Brazil and
that is used as a common gasoline additive in states such as
Colorado and California (http://www.chemweb.com/alchem/articles/994149876998.html).
Ethanol is an oxygen containing chemical that is added to
gasoline to help it burn cleaner.
Current research is looking at different
alternative fuels, such as biodiesel palm oil, and new and
better methods of converting organic matter into ethanol.
The traditional method of producing ethanol involves the
fermentation of glucose into ethanol and carbon dioxide
(http://www.sciencedaily.com/releases/2001/05/010524062508.htm).
A number of factors need to be considered
when producing ethanol through the fermentation of a glucose
solution. For fermentation to occur, the environment should
be anaerobic. Other factors that should be considered are
the amount of sugar needed to produce the highest yield of
ethanol and the temperature needed to maximize anaerobic
respiration or fermentation in yeast.
Fermentation: C6H12O6
6 2 C2H5OH
+ 2 CO2
glucose ethyl alcohol
Links:
http://www.sciencedaily.com/releases/2001/05/010524062508.htm
production of ethanol
http://www.chemweb.com/alchem/articles/992513141289.html
alternative fuels
http://www.sciencedaily.com/releases/1998/08/980824071737.htm
yeast and alcohol production
http://www.chemweb.com/alchem/articles/994149876998.html
ethanol additive in California
Suggested Graphics or Photos: highway and
pollution
Scenario:
You are a member of a research team working
for a company that has decided that ethanol is the fuel of
the future. California has banned the use of methyl-tert-butyl
(MTBE) as a gasoline additive at the end of 2002 and the
only viable alternative is ethanol. Countries throughout the
world are looking for ways to reduce automobile emissions
following the revival of the Kyoto Agreement therefore large
quantities of ethanol could be needed in the near future.
Your company would like to find an efficient method of
producing ethanol and your research team has been asked to
do a presentation for the company that summarizes your
research in the following areas:
#
methods of
manufacturing ethanol
#
production of
ethanol and percentage yield
#
transportation
of product
Part A: Research
1. Use a variety of resources to
research the different techniques currently being used
to produce and transport ethanol. Identify and describe
the different technologies that are involved in the
various stages of production.
2. Use a variety of resources to
research the different techniques currently being used
to produce and transport another alternative fuel
besides ethanol. Make sure you check the topic with your
teacher before proceeding. Identify and describe the
different technologies that are involved in the various
stages of its production.
3. Design a flow chart to show the
stages of production in ethanol and an alternative fuel.
Part B:
Synthesis of Ethanol and Product Testing
4. From the equipment available in your
school, design an apparatus that will allow the
fermentation of glucose Check with your teacher first
before carrying out any investigation. For example, you
could use a gas bottle or flask and a one-hole stopper
in which a piece of bent glass tubing has been inserted
that is attached to a long piece of Tygon tubing. The
end of this tubing is placed under water in a 600 mL
beaker outside of the flask. See Figure 2 at http://www.oxy.edu/departments/tops/Yeast/yeastreference.htm
for a diagram of the anaerobic flask.
5. You must now decide what growing
environment will be best for the yeast to produce the
highest yield of ethanol. You will need to determine the
mass of glucose necessary, the amount of water, the
optimum temperature, and the length of time needed to
allow most of the sugar to be converted to ethanol. This
may require several trials.
6. When you are satisfied that you have
the optimum conditions and that sufficient time has
passed to produce ethanol, remove the ethanol by
distillation.
7. Check the purity of your ethanol
using tests that you have devised and calculate the
percent yield of the ethanol based on the amount of
glucose used initially.
8. Store your ethanol in a labeled
bottle so that it can be used in other experiments.